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Tailoring the microstructure and properties of PES/SPSf loose nanofiltration membranes using SPES as a hydrophilic polymer for the effective removal of dyes via steric hindrance and charge effect

《化学科学与工程前沿（英文）》 2023年第17卷第10期页码 1555-1567 doi: 10.1007/s11705-023-2338-4

摘要： Herein, polyethersulfone (PES) and sulfonated polysulfone (SPSf) blend membranes were prepared with addition of sulfonated polyethersulfone (SPES) as a hydrophilic polymer and adipic acid as a porogen via non-solvent induced phase separation method for effective fractionation of dyes based on the influence of steric hindrance and charge effect. Raman spectroscopy and molecular dynamic simulation modeling confirmed that hydrogen bonds between PES, SPSf, SPES, and adipic acid were crucial to membrane formation and spatial arrangement. Further addition of hydrophilic SPES resulted in a membrane with reduced pore size and molecular weight cut-off as well as amplified negative charge and pure water permeance. During separation, the blend membranes exhibited higher rejection rates for nine types of small molecular weight (269.3–800 Da) dyes than for neutral polyethylene glycol molecules (200–1000 Da). This was attributed to the size effect and the synergistic effect between steric hindrance and charge repulsion. Notably, the synergistic impact decreased with dye molecular weight, while greater membrane negative charge enhanced small molecular dye rejection. Ideal operational stability and anti-fouling performance were best observed in M2 (PES/SPSf/SPES, 3.1 wt %). Summarily, this study demonstrates that SPES with –SO₃^‒ functional groups can be applied to control the microstructure and separation of membranes.

关键词： adipic acid loose nanofiltration membrane dye/salt selective separation steric hindrance charge effect

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Mechanistic insights into the selective photocatalytic degradation of dyes over TiO/ZSM-11

《环境科学与工程前沿（英文）》 2023年第17卷第8期 doi: 10.1007/s11783-023-1701-5

摘要：

● TiO₂/ZSM-11 was prepared by a facile solid state dispersion method.

关键词： Selective dye degradation Photocatalysis TiO₂ ZSM-11 Chemisorption

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Selective capture and separation of xenon and krypton using metal organic frameworks: a review

《化学科学与工程前沿（英文）》 2023年第17卷第12期页码 1895-1912 doi: 10.1007/s11705-023-2355-3

摘要： Xenon and krypton are widespread useful noble gases in commercial lighting, lasers, electronics, and medical industry. At the same time, radioactive noble gases may proliferate from used nuclear fuel and diffuse in open atmospheres. Metal organic frameworks as hotspot porous materials for gases uptake and separation are considered to be potential solutions. In this review, we comprehensively summarized recent researches on metal organic frameworks for selective capture and separation of xenon and krypton. Particularly, we followed the aspects of different optimal design strategies, including optimal pore/cage size and geometry, open metal sites, ions (anions and cations), and polar functional groups for enhancing the xenon adsorption and separation performances. Meanwhile, a comparison of each strategy and the mechanisms of xenon/krypton separation were pointed out. The separation of krypton from gases mixtures by dual-bed systems was further discussed. Finally, some existing challenges and opportunities for possible real applications were proclaimed.

关键词： metal organic frameworks xenon krypton selective separation used nuclear fuel

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Effective and selective separation of perrhenate from acidic wastewater by super-stable, superhydrophobic

《环境科学与工程前沿（英文）》 2022年第16卷第2期 doi: 10.1007/s11783-021-1456-9

摘要：

• A ZnO-biochar hybrid composite was prepared by solvothermal-pyrolysis synthesis.

关键词： Selectivity Adsorption Re(VII) ZnO Biochar

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Highly efficient and selective removal of vanadium from tungstate solutions by microbubble floating-extraction

《化学科学与工程前沿（英文）》 2023年第17卷第5期页码 581-593 doi: 10.1007/s11705-022-2235-2

摘要： Selective separation of dissolved tungsten and vanadium is of great significance for the utilization of the secondary resources of these elements. In this work, selective removal of vanadium from tungstate solutions via microbubble floating-extraction was systematically investigated. The results indicated that vanadium can be more easily mineralized over tungsten from tungstate solutions using methyl trioctyl ammonium chloride as mineralization reagent under weak alkaline conditions. Owing to the higher bubble and interface mass transfer rates, high-efficiency enrichment and deep separation of vanadium could be achieved easily. Additionally, the deep recovery of tungsten and vanadium from the floated organic phase could be easily realized using a mixed solution of sodium hydroxide and sodium chloride as stripping agents. The separation mechanism mainly included the formation of hydrophobic complexes, their attachment on the surface of rising bubbles, and their mass transfer at the oil–water interface. Under the optimal conditions, the removal efficiency of vanadium reached 98.5% with tungsten loss below 8% after two-stage microbubble floating-extraction. Therefore, the microbubble floating-extraction could be an efficient approach for separating selectively vanadium from tungstate solutions, exhibiting outstanding advantages of high separation efficiency and low consumption of organic solvents.

关键词： tungsten vanadium selective separation reagent mineralization microbubble floating-extraction

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Highly efficient and selective removal of phosphate from wastewater of sea cucumber aquaculture for microalgaeculture using a new adsorption-membrane separation-coordinated strategy

《环境科学与工程前沿（英文）》 2023年第17卷第10期 doi: 10.1007/s11783-023-1720-2

摘要：

● A new adsorption-membrane separation strategy is used for phosphate removal.

关键词： Adsorption-membrane Low-concentration phosphate Zr-modified-bentonite Recycle Microalgal culture

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Piezocatalytic performance of FeO−BiMoO catalyst for dye degradation

《化学科学与工程前沿（英文）》 2023年第17卷第6期页码 716-725 doi: 10.1007/s11705-022-2265-9

摘要： A Fe₂O₃−Bi₂MoO₆ heterojunction was synthesized via a hydrothermal method. Scanning electron microscopy, transmission electron microscopy, energy-dispersive X-ray, powder X-ray diffraction, Fourier transform infrared spectroscopy and ultra-violet−visible near-infrared spectrometry were performed to measure the structures, morphologies and optical properties of the as-prepared samples. The various factors that affected the piezocatalytic property of composite catalyst were studied. The highest rhodamine B degradation rate of 96.6% was attained on the 3% Fe₂O₃−Bi₂MoO₆ composite catalyst under 60 min of ultrasonic vibration. The good piezocatalytic activity was ascribed to the formation of a hierarchical flower-shaped microsphere structure and the heterostructure between Fe₂O₃ and Bi₂MoO₆, which effectively separated the ultrasound-induced electron–hole pairs and suppressed their recombination. Furthermore, a potential piezoelectric catalytic dye degradation mechanism of the Fe₂O₃−Bi₂MoO₆ catalyst was proposed based on the band potential and quenching effect of radical scavengers. The results demonstrated the potential of using Fe₂O₃−Bi₂MoO₆ nanocomposites in piezocatalytic applications.

关键词： piezocatalysis Fe₂O₃−Bi₂MoO₆ dye decomposition ultrasonic vibration

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Application of electrode materials and catalysts in electrocatalytic treatment of dye wastewater

《化学科学与工程前沿（英文）》 2021年第15卷第6期页码 1427-1443 doi: 10.1007/s11705-021-2108-0

摘要： The dye industry produces a large amount of hazardous wastewater every day worldwide, which brings potential threaten to the global environment. As an excellent method for removal of water chroma and chemical oxygen demand, electrocatalytic methods are currently widely used in the treatment of dye wastewater. The selection and preparation of electrode materials and electrocatalysts play an important role on the electrocatalytic treatment. The aim of this paper is to introduce the most excellent high-efficiency electrode materials and electrocatalysts in the field of dye wastewater treatment. Many electrode materials such as metal electrode materials, boron-doped diamond anode materials and three-dimensional electrode are introduced in detail. Besides, the mechanism of electrocatalytic oxidation is summarized. The composite treatment of active electrode and electrocatalyst are extensively examined. Finally, the progress of photo-assisted electrocatalytic methods of dye wastewater and the catalysts are described.

关键词： electrocatalytic oxidation electrode electrocatalysis dye wastewater

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盐湖农业及其发展战略研究

孔凡晶,郑绵平,张洪霞,李真,王利伟

《中国工程科学》 2019年第21卷第1期页码 148-152 doi: 10.15302/J-SSCAE-2019.01.021

摘要：

我国是多盐湖国家，拥有丰富的盐沼带及咸水资源，发展盐湖农业对于荒漠化治理、生态环境保护，对发展西部落后地区经济，开拓具有干旱、半干旱地区特色农业，具有现实和长远战略意义。随着全球人口增长，粮食短缺，淡水资源缺乏，充分利用咸水资源及盐碱地资源发展盐湖农业对保障人类食品安全十分必要。本文梳理了近年来在盐湖农业方面的认识及发展成果，指出发展盐湖农业存在的问题，并提出把盐湖农业列入国家科技规划、对盐湖流域盐碱地进行功能区划等创新驱动盐湖农业发展建议。

关键词：盐湖农业盐湖生态系统盐湖生物

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Caloric evaporation of the brine in Zangnan Salt Lake

Shiqiang WANG, Yafei GUO, Nan ZHANG, Lingzhong BU, Tianlong DENG, Mianping ZHENG

《化学科学与工程前沿（英文）》 2011年第5卷第3期页码 343-348 doi: 10.1007/s11705-010-1029-0

摘要： Zangnan Salt Lake on the south of the Tibet is a type of carbonate lake with high concentrations of lithium, boron, and potassium and obviously it differs from seawater in its chemical composition. An experimental simulation of the caloric evaporation of the lake’s brine was conducted by first freezing the brine and then performing isothermal evaporation at 288.15 K. The freezing path and the physicochemical properties of the brine were determined. The crystallization sequence was natron, hydrohalite, halite, sylvite, zabuyelite, trona, aphthitalite, thermonatrite, and borax. Rubidium and cesium salts did not crystallized out but concentrated in the mother solution. The physicochemical properties (density, refractive index, conductivity, and pH) of the liquid phase changed as the evaporation progressed. In the beginning of the evaporation processes, the concentration of potassium ions in the liquid phase gradually increased but later it decreased. A peak value of 55.21 g/L was obtained when the evaporation was 88% complete. When the mineral aphthitalite began to crystallize; the concentrations of B O , Li , Rb , and Cs gradually increased as the evaporation progressed. When the evaporation was 98% complete, their concentrations in the mother liquor were 40.77 g/L, 4.838 g/L, 400.17 mg/L and 31.95 mg/L, respectively. This essential fundamental study can provide an important reference for the comprehensive utilization of brines in Zangnan Salt Lake.

关键词： Zangnan Salt Lake evaporation crystallization path freezing

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Decolorization of azo dyes by a salt-tolerant

Bin YAN, Cuihong DU, Meilan XU, Wenchao LIAO

《环境科学与工程前沿（英文）》 2012年第6卷第6期页码 806-814 doi: 10.1007/s11783-012-0453-4

摘要： The salt-tolerant strain, isolated from textile wastewater, has been found effective on decolorizing several kinds of azo dyes with different structures. The optimal conditions for azo dye acid red B (ARB) decolorization by were determined to be pH= 7.0 and 30°C. The decolorization efficiency increased with the increase of the salinity concentration, and around 90% of ARB (100 mg·L ) could be decolorized in 24 h when the salinity concentration was up to 50 g·L . Moreover, the strain could still decolorize 19% of ARB in 24 h even when the NaCl concentration was increased to 150 g·L . Meanwhile, the dependence of the specific decolorization rate by on the ARB concentration could be described with Michaelis-Menten kinetics ( = 585.7 mg·L , = 109.8 mg·g cell ·h ). The addition of quinone redox mediator, named 2-hydroxy-1,4-naphthoquinone and anthraquinone-2,6-disulfonate, significantly accelerated the decolorization performance of . Furtherly, the activities of azoreductase (0.55 μmol·mg protein ·min ) and Nicotineamide adenine dinucleotide-dichlorophenol indophenol (NADH-DCIP) reductase (8.9 μmol·mg protein ·min ) have been observed in the crude cell extracts of . The decolorization products of ARB were analyzed by HPLC-MS, and the results indicated the reductive pathway was responsible for azo dye decolorization by .

关键词： Staphylococcus cohnii decolorization salt azoreductase Nicotineamide adenine dinucleotide-dichlorophenol indophenol (NADH-DCIP) reductase

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Assessment of future climate change impacts on water-heat-salt migration in unsaturated frozen soil using

Hanli Wan, Jianmin Bian, Han Zhang, Yihan Li

《环境科学与工程前沿（英文）》 2021年第15卷第1期 doi: 10.1007/s11783-020-1302-5

摘要： Abstract • A model coupling water-heat-salt of unsaturated frozen soil was established. • Future temperature, precipitation, and evaporation increase in freeze–thaw period. • Soil water, heat, and salt transport are closely coupled during freeze–thaw period. • Freeze–thaw cycles and future climate change can exacerbate salinization. The transport mechanisms of water, heat, and salt in unsaturated frozen soil, as well as its response to future climate change are in urgent need of study. In this study, western Jilin Province in north-eastern China was studied to produce a model of coupled water-heat-salt in unsaturated frozen soil using CoupModel. The water, heat, and salt dynamics of unsaturated frozen soil under three representative concentration pathway (RCP) scenarios were simulated to analyze the effects of future climate change on unsaturated frozen soil. The results show that water, heat, and salt migration are tightly coupled, and the soil salt concentration in the surface layer (10 cm) exhibits explosive growth after freezing and thawing. The future (2020–2099) meteorological factors in the study area were predicted using the Statistical Downscaling Model (SDSM). For RCP2.6, RCP4.5, and RCP8.5 scenarios, future temperatures during the freeze–thaw period increased by 2.68°C, 3.18°C, and 4.28°C, respectively; precipitation increased by 30.28 mm, 28.41 mm, and 32.17 mm, respectively; and evaporation increased by 93.57 mm, 106.95 mm, and 130.57 mm, respectively. Climate change will shorten the freeze–thaw period, advance the soil melting time from April to March, and enhance water and salt transport. Compared to the baseline period (1961–2005), future soil salt concentrations at 10 cm increased by 1547.54 mg/L, 1762.86 mg/L, and 1713.66 mg/L under RCP2.6, RCP4.5, and RCP8.5, respectively. The explosive salt accumulation is more obvious. Effective measures should be taken to prevent the salinization of unsaturated frozen soils and address climate change.

关键词： Soil salinization Climate change Unsaturated frozen soil Water-heat-salt balance Soil environment change

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Size and shape effects of MnFeO nanoparticles as catalysts for reductive degradation of dye pollutants

《环境科学与工程前沿（英文）》 2021年第15卷第5期页码 108-171 doi: 10.1007/s11783-021-1396-4

摘要： The magnetic nanoparticles that are easy to recycle have tremendous potential as a suitable catalyst for environmental toxic dye pollutant degradation. Rationally engineering shapes and tailoring the size of nanocatalysts are regarded as an effective manner for enhancing performances. Herein, we successfully synthesized three kinds of MnFe₂O₄ NPs with distinctive sizes and shapes as catalysts for reductive degradation of methylene blue, rhodamine 6G, rhodamine B, and methylene orange. It was found that the catalytic activities were dependent on the size and shape of the MnFe₂O₄ NPs and highly related to the surface-to-volume ratio and atom arrangements. Besides, all these nanocatalysts exhibit selectivity to different organic dyes, which is beneficial for their practical application in dye pollutant treatment. Furthermore, the MnFe₂O₄ NPs could be readily recovered by a magnet and reused more than ten times without appreciable loss of activity. The size and shape effects of MnFe₂O₄ nanoparticles demonstrated in this work not only accelerate further understanding the nature of nanocatalysts but also contribute to the precise design of nanoparticles catalyst for pollutant degradation.

关键词： Dye degradation MnFe₂O₄ nanoparticles Size and shape-control

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Hydraulic properties of typical salt-affected soils in Jiangsu Province, China

CHEN Xiaomin, SHEN Qirong, XU Yangchun

《环境科学与工程前沿（英文）》 2007年第1卷第4期页码 443-447 doi: 10.1007/s11783-007-0070-9

摘要： Every year about 1,500 ha of land is reclaimed from the sea along the coastline of Jiangsu Province, China. It is important to characterize the hydraulic properties of this reclaimed land to be able to predict and manage salt and wa

关键词： hydraulic Jiangsu Province coastline important reclaimed

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Impacts of de-icing salt pollution on urban road greenspace: a case study of Beijing

Zhouyuan LI,Yingmei LIANG,Junhui ZHOU,Xiao SUN

《环境科学与工程前沿（英文）》 2014年第8卷第5期页码 747-756 doi: 10.1007/s11783-014-0644-2

摘要： De-icing salt contamination of urban soil and greenspace has been a common issue of concern in many countries for years. In the 2009/2010 winter, Beijing experienced a contamination accident resulting from the overuse of de-icing salt, reported as almost 30000 tons, which severely damaged urban vegetation alongside roadways. The methods of sampling and rating for both soil contamination and response of the plant populations were developed to rapidly assess this emergency environmental event. Results showed that the shrubs were more severely damaged than the arbors in terms of both degree and extent, as almost all of the surveyed shrubs were severely damaged from the salt contamination, while only about 1/4 of the recorded arbors were rated as “severely injured” according to the integral plant injury index. The rating of the injury level showed that the trees like a, , and the shrubs like , showed less tolerance to de-icing salt pollution. The patterns of vegetation damage demonstrated that the ever-green shrubs alongside roads and the deciduous arbors in the center of roads were most vulnerable to the salt damage.

关键词： de-icing salt environmental impact assessment urban ecology greenspace

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标题作者时间类型操作

Tailoring the microstructure and properties of PES/SPSf loose nanofiltration membranes using SPES as a hydrophilic polymer for the effective removal of dyes via steric hindrance and charge effect

期刊论文

Mechanistic insights into the selective photocatalytic degradation of dyes over TiO/ZSM-11

期刊论文

Selective capture and separation of xenon and krypton using metal organic frameworks: a review

期刊论文

Effective and selective separation of perrhenate from acidic wastewater by super-stable, superhydrophobic

期刊论文

Highly efficient and selective removal of vanadium from tungstate solutions by microbubble floating-extraction

期刊论文

Highly efficient and selective removal of phosphate from wastewater of sea cucumber aquaculture for microalgaeculture using a new adsorption-membrane separation-coordinated strategy

期刊论文

Piezocatalytic performance of FeO−BiMoO catalyst for dye degradation

期刊论文

Application of electrode materials and catalysts in electrocatalytic treatment of dye wastewater

期刊论文

盐湖农业及其发展战略研究

孔凡晶,郑绵平,张洪霞,李真,王利伟

期刊论文

Caloric evaporation of the brine in Zangnan Salt Lake

Shiqiang WANG, Yafei GUO, Nan ZHANG, Lingzhong BU, Tianlong DENG, Mianping ZHENG

期刊论文

Decolorization of azo dyes by a salt-tolerant